Synthesis and Characterization of Chitosan-Silica Membranes for Treating Hotel Wastewater Treatment as Affected by Mass of Poly Ethylene Glycol and Poly Vinyl Alcohol
DOI:
https://doi.org/10.31258/Jamt.1.1.31-37Keywords:
chitosan, flux, membrane, silica, wastewaterAbstract
Chitosan-Silica blended membranes were an attractive choice for the purification process because their porous size and morphology provide higher selectivity. In this study, the synthesis and characterization of chitosan-silica membranes were carried out with a mass variation of Poly Ethylene Glycol (PEG): 0,5; 2,5; 5 grams, Poly Vinyl Alcohol (PVA): 1, 2, 3 grams; and pressure 1, 2, 3 bars for the hotel wastewater treatment. The purpose of this study was to determine the characterization of chitosan-silica membranes obtained by SEM and tensile strength, and to determine the performance of membrane against the flux and rejection test with the effect of a mixture of PEG and PVA mass using raw materials in form of chitosan-silica. Tensile strength analysis showed that membrane with the highest tensile strength was 19,14 Mpa for PEG and 13,7 Mpa for PVA. The SEM test results showed a relatively small pore size of PEG 0,5 gram (0,061 ?m) and PVA 2 grams (0,0284 ?m). Flux and rejection results showed that membrane with 2,5 grams composition of PEG was the most effective in performance with the flux 18,19 L/m2.h and rejection elimination of BOD (50,76%), COD (46,09%) and TSS (48,00%). On the other hand, flux results showed that membrane with 3 grams composition of PVA was the most effective with the flux 20,13 L/m2.h and rejection elimination of BOD (62,84%), COD (64,73%) and TSS (38,40%). The characteristics of permeability, selectivity, and membrane pore statistics show that the silica membrane is an ultrafiltration membrane.
Downloads
References
Arifin, M., Starred Hotel Waste Treatment (Case Study in South Jakarta). 2000.
Yuan, W., et al., Sorbitol-plasticized chitosan/zeolite hybrid membrane for direct methanol fuel cell. Journal of Power Sources, 2007. 172(2): p. 604-612.
Wu, Y., et al., PVA–silica anion-exchange hybrid membranes prepared through a copolymer crosslinking agent. Journal of Membrane Science, 2010. 350(1-2): p. 322-332.
Arthanareeswaran, G., D. Mohan. Dan M. Raajenthiren, Preaparatoin, Characterization and Perfomance Studies of Ultrafiltration Membranes with Polymeric Additive. Journal of Membrane Science, 2010. 350: p. 130-138.
Ma, Y., F. Shi, J. Ma, M. Wu, J. Zhang dan C. Gao, Effect of PEG Additive on the Morphology and Performance of Polysulfone Ultrafiltration Membranes. Desalination, 2011. 272: p. 51-58.
Hyder, M. and P. Chen, Pervaporation dehydration of ethylene glycol with chitosan–poly (vinyl alcohol) blend membranes: effect of CS–PVA blending ratios. Journal of Membrane Science, 2009. 340(1-2): p. 171-180.
Wahyuningsih, S., A.H. Ramelan, D.T. Wardoyo, S. Ichsan dan Y.R. Kristiawan, Influence of Polyvinyl Alcohol (PVA) Addition on Silica Membrane Performance Prepared from Rice Straw. Materials Science and Engineering, 2017. 333.
Cheng, Z.L., S.C. Zi, Q.L. Hai dan L.W. Hui, NaA Zeolite Membrane with High Performance Synthesized by Vapor Phase Transformation Method. Chinese Journal of Chemistry 2010. 11: p. 1430-1432.
HIDUP, P.A.P.M.L., T.P.H.H.K. YANG, and B.D.H. ALAM, PERATURAN MENTERI LINGKUNGAN HIDUP DAN KEHUTANAN REPUBLIK INDONESIA. 2016.
Wu, Y., et al., Cation exchange PVA/SPPO/SiO2 membranes with double organic phases for alkali recovery. Journal of membrane science, 2012. 423: p. 383-391.
Mulder, M., Basic Principles of Membrane Technology, 2nd EdKluwer Academic Publishers. Boston, MA, 1996.
Liu, J., et al., Preparation and characterization of chitosan/Cu (II) affinity membrane for urea adsorption. Journal of Applied Polymer Science, 2003. 90(4): p. 1108-1112.
Zou, S.B., et al., Loss of elongation factor P disrupts bacterial outer membrane integrity. Journal of bacteriology, 2012. 194(2): p. 413-425.
Nguyen, H.M., Preparation and Applications of CNT-PVA/Nafion for PEMFCs. 2011.
Kusumawati, N. and S. Tania, Pembuatan dan uji kemampuan membran kitosan sebagai membran ultrafiltrasi untuk pemisahan zat warna Rhodamin B. Molekul, 2012. 7(1): p. 43-52.
Lee, K.-M. and Y.-M. Jo, Synthesis of zeolite from waste fly ash for adsorption of CO 2. Journal of Material Cycles and Waste Management, 2010. 12(3): p. 212-219.
Lusiana, R.A., et al., Chitosan-Tripoly Phosphate (CS-TPP) Synthesis Through Cross-linking Process: the Effect of Concentration Towards Membrane Mechanical Characteristic and Urea Permeation. Oriental Journal of Chemistry, 2017. 33(6): p. 2913-2919.
Al-Moudi, A.d.L., R.W, Fouling Strategist and The Cleaning System of NF Membranes and Factors affecting Cleaning Efficiency. Journal of Membranes Science, 2007. 303: p. 4-28.
Published
Issue
Section
License
Copyright (c) 2019 Jhon Armedi Pinem, Dessy Natalia Indah Panjaitan, M. Rifai Siregar, Edy Saputra, Syamsu Herman

This work is licensed under a Creative Commons Attribution 4.0 International License.









